it might not be the simple matter of just changing the valves and putting a new belt on, the head could be damaged if the valves have smashed into them and the same goes for the pistons, they could be damaged due to the valves hitting them.
VW charge £5 per head bolt which adds up, i have always used GSF standard non G40 ones (G40 ones are 1mm longer) and they are £1 each.
As for the headgasket its around £25 for a genuine one but might be worth changing it for a metal one from a 6n which is around £15.